Chemistry, Physics and Technology of Surface, 2012, 3 (4), 419-428.

Ion-Exchange Properties of Modified Silica with Bound Amides of Polyhexamethyleneguanidine and Maleic or o-Phthalic Acids



A. D. Dadashev, V. A. Tertykh, E. S. Yanovska, K. V. Yanova

Abstract


Amides of polyhexamethyleneguanidine and maleic or o-phthalic acids were chemically bound with the silica surface. Adsorption properties of synthesized modified silicas have been studied with respect to V(V)-, Cr(VI)-, Mo(VI)-, and W(VI)-containing anions. Both of adsorbents were found to show high adsorption activity in the acidic and slightly acidic media. Kinetic parameters of the obtained composites are closely similar to a polymeric adsorbent. Reduction of Mo(VI) and Cr(VI) ions was detected at adsorption on silica with bound amide of polyhexamethyleneguanidine and o-phthalic acid. The investigation demonstrates the possibility of the quantitative determination of microamounts of the studied metals in the adsorbent phase using the X-ray-fluorescence analysis after extraction of anions from a solution.

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