Chemistry, Physics and Technology of Surface, 2015, 6 (1), 56-66.

Adsorption of Organic Anions and Cations from Aqueous Solutions on Organosubstituted Layered Silicates



DOI: https://doi.org/10.15407/hftp06.01.056

Yu. I. Tarasevich, M. Yu. Tryfonova

Abstract


The results of adsorption and spectral studies on the interaction of organic anions and cations with organosubstituted layered silicates are generalized; schemes of adsorption mechanisms are proposed. It is proved that the adsorption of organic anions is carried out due to formation of ionic associates with modifiers. Thus, the unknown fact is found – in case of the silicates substituted with long chain cationic surfactants, a desorption of the modifier and its secondary adsorption as a part of ionic associates to organic anions takes place. It has been found that large organic cations are physically adsorbed on the surface of cationic surfactant-substituted silicates and on the polycation-substituted ones – by ion exchange mechanism.

Keywords


layered silicates; modifier; cationic surfactant; cationic polyelectrolyte; adsorption; dyes; organic anions; organic cations; ion associates; adsorbed dye spectra

Full Text:

PDF (Русский)

References


1. Kurilenko O.D., Mikhaylyuk R.V. Adsorption on bentonite aliphatic amines from aqueous solutions. Colloid Journal. 1959. 21(2): 181. [in Russian].

2. Gudovich N.V., Ovcharenko F.D. Education organophilic montmorillonite with ion exchange. Colloid Journal. 1963. 25(4): 407. [in Russian].

3. Lee S.M, Tiwari D. Organo and inorgano-organo-modified clays in the remediation of aqueous solutions: An overview. Appl. Clay Sci. 2012. 59–60: 84.   https://doi.org/10.1016/j.clay.2012.02.006

4. Alkaram U.F., Mukhlis A.A., Al-Dujaili A.H. The removal of phenol from aqueous solutions by adsorption using surfactant-modified bentonite and kaolinite. J. Hazard. Mater. 2009. 169(1–3): 324.   https://doi.org/10.1016/j.jhazmat.2009.03.153

5.  Akcay G., Yurdako K. Removal of various phenoxyalkanoic acid herbicides from water by organo-clays. Acta Hydroch. Hydrob. 2000. 28(6): 300.   https://doi.org/10.1002/1521-401X(200012)28:6<300::AID-AHEH300>3.0.CO;2-L

6. Kang Q., Zhou W., Li Q., Yu G.B., Xin F.J., Zhong Sh.D. Adsorption of anionic dyes on poly(epicholorohydrin dimethylamine) modified bentonite in single and mixed dye solutions. Appl. Clay Sci. 2009. 45(4): 280.   https://doi.org/10.1016/j.clay.2009.06.010

7. Sanchez-Martin M.J., Rodriguez-Cruz M.S., Andrades M.S., Sanchez-Camazano M. Efficiency of different clay minerals modified with a cationic surfactant in the adsorption of pesticides: influence of clay type and pesticide hydrophobicity. Appl. Clay Sci. 2006. 31(3–4): 216.   https://doi.org/10.1016/j.clay.2005.07.008

8. Wang L., Wang A. Adsorption properties of congo red from aqueous solution onto surfactant-modified montmorillonite. J. Hazard. Mater. 2008. 160(1): 173.   https://doi.org/10.1016/j.jhazmat.2008.02.104

9. Beall G.W. The use of organo-clays in water treatment. Appl. Clay Sci. 2003. 24(1–2): 11.  https://doi.org/10.1016/j.clay.2003.07.006

10. Lee S.Y., Kim S.J. Adsorption of naphthalene by HDTMA modified kaolinite and halloysite. Appl. Clay Sci. 2002. 22(1–2): 55.  https://doi.org/10.1016/S0169-1317(02)00113-8

11. Li Q., Yue Q.Y., Su Y., Gao B.Y., Fu L. Cationic polyelectrolyte/bentonite prepared by ultra-sonic technique and its use as adsorbent for Reactive Blue K-GL dye. J. Hazard. Mater. 2007. 147(1–2): 370.   https://doi.org/10.1016/j.jhazmat.2007.01.024

12. Ozcan A.S., Erdem B., Ozcan A. Adsorption of Acid Blue 193 from aqueous solutions onto Na–bentonite and DTMA–bentonite. J. Colloid Int. Sci. 2004. 280(1): 44.   https://doi.org/10.1016/j.jcis.2004.07.035

13. Wang C.C., Juang L.C., Lee C.K., Hsua T.-Ch., Leeb J.-F. Effects of exchanged surfactant cations on the pore structure and adsorption characteristics of montmorillonite. J. Colloid Int. Sci. 2004. 280(1): 27.  https://doi.org/10.1016/j.jcis.2004.07.009

14. Ceyhan O., Baybaş D. Adsorption of some textile dyes by hexadecyltrimethlyammonium bentonite. Turk. J. Chem. 2001. 25(2): 193.

15. Tarasevich Yu.I., Doroshenko V.Yu., Bondarenko S.V., Zhukova A.I. Spectral Study Association of cationic surfactants in solution and on the solid surface. Colloid Journal. 1985. 47(1): 99. [in Russian].

16. Tarasevich Yu.I., Trifonova M.Yu., Bondarenko S.V., Didenko S.A. Interaction of crystal violet with natural and organic cations modified layered silicates. Colloid Journal. 2010. 72(4): 555. [in Russian].https://doi.org/10.1134/S1061933X10040198 

17. Trifonova M.Yu., Didenko S.A., Bondarenko S.V., Tarasevich Yu.I. Adsorption of organic anions from aqueous solutions layered silicates modified with cationic surfactants. Colloid Journal. 2011. 73(4): 529. [in Russian].   https://doi.org/10.1134/S1061933X11030148

18. Trifonova M.Yu., Dolenko S.A., Tarasevich Yu.I., Bondarenko S.V., Zhukova A.I. Absorption of organic anions from aqueous solutions by layer silicates substituted with a cationic electrolyte. J. Water Chem. Technol. 2011. 33(5): 281.   https://doi.org/10.3103/S1063455X1105002X

19. Tarasevich Yu.I., Ovcharenko F.D. Adsorption on clay minerals. (Kyev: Naukova dumka, 1975). [in Russian].

20. Trifonova M.Yu., Tarasevich Yu.I., Bondarenko S.V., Dolenko S.A., Ivanova Z.G., Zhukova A.I. Structure-sorption properties of natural layer silicates and layer silicates modified by cationic SAS with a rigid structural cell. J. Water Chem. Technol. 2008. 30(3): 161.   https://doi.org/10.3103/S1063455X08030053

21. Trifonova M.Yu., Tarasevich Yu.I., Bondarenko S.V., Zhukov A.I., Ivanova Z.G. Production and structural-sorption properties of alumosilicates with a hard structural cell modified with polyelectrolyte. J.Water Chem. Technol. 2009. 31(3): 149.  https://doi.org/10.3103/S1063455X09030023

22. Tarasevich Yu.I., Trifonova M.Yu., Aksenenko E.V. Modification of Natural Layered Silicates with Rigid Structure by Polyhexamethylene Guanidine. Theor. Exp. Chem. 2013. 49(3): 193.   https://doi.org/10.1007/s11237-013-9314-x

23. Didenko S.A., Zaporozhets O.A., Shevchenko V.V., Kushchevskaya N.F. Sorption-Photometric Determination of cationic surfactants in the water. Khimiya i tekhnologiya vody. 2006. 28(2): 125. [in Russian].

24. Goncharuk V.V., Terletskaya A.V., Iyevleva O.S., Bogoslovskaya T.A., Kushchevskaya N.F. A new photometric method for the determination of residual polyhexamethyleneguanidine concentrations in drinking and natural waters. Khimiya i tekhnologiya vody. 2006. 28(6): 558. [in Russian].

25. Lurie Yu.Yu. Analytical chemistry and industrial waste water. (Moscow: Khimiya, 1984). [in Russian].

26. Runov V.A., Tropinina V.V. Optical sorption-molecular spectroscopy-cal analysis methods. Methodological issues of quantitative measurements in diffuse reflectance spectroscopy. Zhurnal Analiticheskoi Khimii. 1996. 51(1): 71. [in Russian].

27. Tarasevich Yu.I. The structure and surface chemistry of layered silicates. (Kyev: Naukova dumka, 1988). [in Russian].

28. Tarasevich Yu.I. Natural sorbents in water purification processes. (Kyev: Naukova dumka, 1981). [in Russian].

29. Terenin A.N. Photonics dye molecules. (Leningrad: Nauka, 1967). [in Russian].




DOI: https://doi.org/10.15407/hftp06.01.056

Copyright (©) 2015 Yu. I. Tarasevich, M. Yu. Tryfonova

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.