Email the author Comparison of sorption properties towards toxic metal ions of organomineral composites based on vermiculite with in situ immobilized and adsorbed poly [8-oxyquinoline methacrylate]
DOI: https://doi.org/10.15407/hftp13.03.289
Abstract
The purpose of the work is synthesis of new organomineral composites by in situ immobilization and adsorption of poly[8-methacroyloxy-quinoline] on the surface of vermiculite and study of sorption properties of cations Cu(II), Pb(II) and Fe(III). In situ immobilization of poly [8-oxyquinolinemethacrylate] on the surface of vermiculite was carried out by initiated radical polymerization of 8 oxyquinoline methacrylate using 2,2′-azobisisobutyronitrile (AIBN) as a dinitrile initiator in the presence of vermiculite. To obtain the composite by adsorption of poly[8-oxyquinolinemethacrylate] on the surface of vermiculite, the polymer was synthesized in advance, then dissolved in tetrahydrofuran and adsorbed on vermiculite. The fact of immobilization of poly[8-oxyquinolinemethacrylate] on the surface of vermiculite was confirmed by comparative analysis of the IR spectra of the source mineral and relative composites. The regularities of thermal decomposition of immobilized polymer were studied by thermogravimetric analysis combined with mass spectrometry. Using the results of low-temperature adsorption-desorption of nitrogen and scanning electron microscopy, changes in the morphology of the vermiculite surface after immobilization of poly[8-oxyquinolinemethacrylate] by the selected methods are shown. The sorption characteristics of the synthesized composites with respect to Cu(II), Pb(II) and Fe(III) ions were examined in static mode. The polymer with oxyquinoline groups immobilized on the surface of vermiculite showed sorption activity against those metal ions with which 8-oxyquinoline forms stable complexes, the sorption capacity relative to cations Cu(II) is doubled after in situ immobilization of poly [8-oxyquinoline methacrylate] on the surface of vermiculite and increases almost 3 times after adsorption of this polymer. For Pb(ІІ) ions this effect is lower: after in situ immobilization of [8-methacroyloxy-quinoline] sorption capacity increases by one-third and as the result, the increasing of adsorption of this polymer is insignificant and is within the experimental accuracy.
Keywords
Full Text:
References
Shiqing Gu, Xiaonan Kang, Lan Wang, Eric Lichtfouse, Chuanyi Wang. Clay mineral adsorbents for heavy metal removal from wastewater: a review. Environ. Chem. Lett. 2019. 17(2): 629. https://doi.org/10.1007/s10311-018-0813-9
Mohammad Kashif Uddin. A review on the adsorption of heavy metals by clay minerals with special focus on the past decade. Chem. Eng. J. 2017. 308: 438. https://doi.org/10.1016/j.cej.2016.09.029
Petrenko O.V., Yanovska E.S., Terebilenko K.V., Stus N.V. Green chemistry. (Kyiv: Kyiv University, 2020). [in Ukraine].
Ryabchenko K.V., Yanovska E.S., Tertykh V.A., Kichkiruk O.Yu., Sternik D. Adsorption properties of vermiculite with in situ immobilized polyaniline with respect to Cr(VI), Mo(VI), W(VI), V(V) and P(V) anions. Adsorp. Sci. Technol. 2014. 32(1): 88. https://doi.org/10.1260/0263-6174.32.1.89
Borodavka T.V. Ph.D (Chem.). Thesis. (Kyiv, 2011). [in Ukrainian].
Barabaszová K.Č. Characterization of vermiculite particles after different milling techniques. Powder Technol. 2013. 239: 277. https://doi.org/10.1016/j.powtec.2013.01.053
Biletsky V.S. Smoll mining encyclopedia. (Donetsk: Donbass), 2004.
Fonseca M., Oliveira M., Arakaki L., Espinola J., Airoldi C. Natural vermiculite as an exchanger support for heavy cations in aqueous solution. J. Colloid Interface Sci. 2005. 285(1): 50. https://doi.org/10.1016/j.jcis.2004.11.031
Marcos C. X-ray diffraction studies of the thermal behaviour of commercial vermiculites. Appl. Clay Sci. 2009. 42(3-4): 368. https://doi.org/10.1016/j.clay.2008.03.004
Bergaya F. Handbook of clay. (Amsterdam: Elsevier), 2006.
Buriachenko I., Yanovska E., Vretik L., Sternik D., Kychkiruk O., Nikolaeva O. In situ polymerization of 4-(methacryloylamino) phenyl-2-methylacrylate on the surface of silica gel. French-Ukrainian Journal of Chemistry. 2016. 4(2): 47. https://doi.org/10.17721/fujcV4I2P47-54
Buriachenko I., Yanovska E., Savchenko I., Sternik D., Kychkiruk O., Ol'khovik L. In situ immobilization on the silica gel surface and adsorption capacity of poly N-4-carboxyphenyl)methacrylamide on toxic metals ions. Nanoscale Res. Lett. 2017. 12(1): 313. https://doi.org/10.1186/s11671-017-2066-0
Polonska Y., Yanovska E., Savchenko I., Sternik D., Kychkiruk O., Ol'khovik L. In situ immobilization on the silica gel surface and adsorption capacity of polymer based azobenzene on toxic metal ions. Appl. Nanosci. 2019. 9(5): 657. https://doi.org/10.1007/s13204-018-0734-8
Polonska Y., Yanovska E., Savchenko I., Sternik D., Kychkiruk O., Ol'khovik L. Sorption properties for ions of toxic metals of carpathian clinoptilolite (Ukraine), in situ modified by poly[n-(4-carboxyphenyl) methacrylamide]. New Mater. Compd. Appl. 2017. 1(1): 45.
Polonska Y., Yanovska E., Savchenko I., Sternik D., Ol'khovik L., Kychkiruk O. Sorption properties of toxic metal ions of saponite, in situ modified poly [n- (4-carboxyphenyl) methacrylamide]. Ukr. Chem. J. 2018. 84(2): 67. [in Ukrainian].
Polonska Y., Yanovska E., Savchenko I., Sternik D., Kychkiruk O., Ol'khovik L. In situ immobilization on the silica gel surface and adsorption capacity of poly[4-methacroyloxy-(4′-carboxy-2′-nitro)-azobenzene] on toxic metals ions. Mol. Cryst. Liq. Cryst. 2018. 671(1): 164. https://doi.org/10.1080/15421406.2018.1542099
Polonska Y., Yanovska E., Savchenko I., Sternik D., Kychkiruk O., Ol'khovik L. Azocontaining polymers, in situ immobilized on the silica gel surface. Mol. Cryst. Liq. Cryst. 2018. 673(1): 39. https://doi.org/10.1080/15421406.2019.1578492
Babko A.K., Pilipenko A.T. Photometric analysis. (Moscow: Chemistry, 1968). [in Russian].
Yanovska E.S., Tertykh V.A., Kichkiruk O.Yu., Dadashev A.D. Adsorption and complexing properties of silicas with analytical reagents grafted via the Mannich reaction. Adsorp. Sci. Technol. 2007. 25(1-2): 81. https://doi.org/10.1260/026361707781485726
Yanovskaya E.S., Slobodyanik N.S., Karmanov V.I. Features of X-ray fluorescence determination of traces of toxic metals with preliminary extraction and concentration on silica gel chemically modified by mercapto groups. J. Anal. Chem. 2007. 62(6): 611. https://doi.org/10.1134/S1061934807060093
Moawed E.A., Moawed E.A., Zaid M.A.A., El-Shahat M.F. Analytical application of polyurethane foam functionalized with quinolin-8-ol for preconcentration and determination of trace metal ions in wastewater. J. Anal. Chem. 2006. 61(5): 499. https://doi.org/10.1134/S1061934806050054
Gurnani V., Gurnani V., Singh A.K., Venkataramani B. Cellulose functionalized with 8 hydroxyquinoline: new method of synthesis and applications as a solid phase extractant in the determination of metal ions by flame atomic absorption spectrometry. Anal. Chim. Acta. 2003. 485(2): 221. https://doi.org/10.1016/S0003-2670(03)00416-1
Martins A.O., Silva E.L., Laranjeira M.C.M., Valfredo T. de Fávere. Application of chitosan functionalized with 8-hydroxyquinoline: Determination of lead by flow injection flame atomic absorption spectrometry. Microchimica Acta. 2005. 150(1): 27. https://doi.org/10.1007/s00604-005-0336-5
Smith A.L. Applied IR spectroscopy. (Moscow: Mir, 1982). [in Russian].
DOI: https://doi.org/10.15407/hftp13.03.289
Copyright (©) 2022 E. S. Yanovska, I. O. Savchenko, O. Yu. Kychkyruk
This work is licensed under a Creative Commons Attribution 4.0 International License.