Anodic aluminum oxide-membrane prepared in electrolyte “oxalic acid – matter with carbon nanodots”
DOI: https://doi.org/10.15407/hftp14.02.237
Abstract
Anodic porous alumina has been studied and used as nanoscale structure, coating, template in different applications. The porous anodic alumina oxide could be described as numerous hexagonal cells and looks like cellular structure. In this work we report about results of study anodizing of aluminum with usage of electrolyte: “oxalic acid electrolyte-matter with carbon nanodots”. It was received anodic aluminum oxide-membrane with aluminum supporting; calcination was used as post treatment. The aluminum substrate allows one to fix the membrane in the cells. Methods: processes of anodizing was provided in 0.3M oxalic acid with addition of colloid system of carbon nanodots, temperature of process was controlled at range of 10 degree Celsius, aluminum foil (anode) and platinum plate (cathode) were used; thickness of aluminum foil was 0.1 µm; morphology and structure of anodic aluminum oxide-membrane were determined with usage of electron scanning microscope; the contact angle between the surface of anodic aluminum oxide-membrane and deionized water was measured with “drop” methodology. Calcium content was monitored with a conductometer. The content of proteins was determined with photometry (micro Lowry’s method). It was found that contact angle of the surface of anodic aluminum oxide-membrane obtained in electrolyte “oxalic acid-matter with carbon nanodots” and deionized water is 38 degrees. Adding colloidal system of carbon nanodots to the acid electrolyte acts as a hydrophilizer, changes the size of the porous surface: as a result, it is possible to control the porosity of the films. Calcination of anodic aluminum oxide-membrane at 500 degree Celsius lead to expansion and thinning of pore walls. Anodic aluminum oxide-membrane was tested for dialysis process for milk whey separation. The membrane obtained in electrolyte: “oxalic acid-matter with carbon nanodots” showed a greater degree of rejection of protein particles in comparison with a similar membrane obtained in electrolyte of oxalic acid. The advantage of using carbon nanodots in acid electrolyte is the simplicity and environmental friendliness of the synthesis. The approach, which involves the addition of a colloidal system with carbon nanomaterial, allows one to avoid using a strongly acidic electrolyte for obtaining membranes with smaller pores. One of the ways for using of anodic oxide aluminum-membrane is the dialysis of biological fluids, for example, milk whey.
Keywords
References
Hull T.R., Witkowski A., Hollingbery L. Fire retardant action of mineral fillers. Polym. Degrad. Stab. 2011. 96(8): 1462. https://doi.org/10.1016/j.polymdegradstab.2011.05.006
Patent US 4415412. Vandegrift G.F., Horwitz P., Krumpelt M. Production of anhydrous aluminum chloride composition and process for electrolysis thereof. 1983.
Mohamed R.M., Ismail A.A., Kini G., Ibrahim I.A., Koopman B. Synthesis of highly ordered cubic zeolite A and its ion-exchange behavior. Colloids Surf., A. 2009. 348(1-3): 87. https://doi.org/10.1016/j.colsurfa.2009.06.038
Das B.R., Dash B., Tripathy B.C., Bhattacharya I.N., Das S.C. Production of η-alumina from waste aluminium dross. Miner. Eng. 2007. 20(3): 252. https://doi.org/10.1016/j.mineng.2006.09.002
Hsieh S.-M., Liu M.-Ch., Chen Y.-H., Lee W.-S., Hwang Sh.-J., Cheng Sh.-H., Ko W.-Ch., Hwang K.-P., Wang N.-Ch., Lee Yu-L., Lin Yi-L., Shih Sh.-Ru, Huang Ch.-G., Liao Ch.-Che, Liang J.-J., Chang Ch.-Sh., Chen Ch., Lien Ch. En, Tai I-Ch., Lin T.-Y. Safety and immunogenicity of CpG 1018 and aluminium hydroxide-adjuvanted SARS-CoV-2 S-2P protein vaccine MVC-COV1901: interim results of a large-scale, double-blind, randomised, placebo-controlled phase 2 trial in Taiwan. Lancet Respir. Med. 2021. 9(12):1396. https://doi.org/10.1016/S2213-2600(21)00402-1
Fleagle Chisholm C., Jin Kang T., Dong M., Lewis K., Namekar M., Lehrer A.T., Randolph T.W. Thermostable ebola virus vaccine formulations lyophilized in the presence of aluminum hydroxide. Eur. J. Pharm. Biopharm. 2019. 136: 213. https://doi.org/10.1016/j.ejpb.2019.01.019
Zotov R., Meshcheryakov E., Livanova A., Minakova T., Magaev O., Isupova L., Kurzina I. Influence of the composition, structure, and physical and chemical properties of aluminium-oxide-based sorbents on water adsorption ability. Materials. 2018. 11(1): 132. https://doi.org/10.3390/ma11010132
Danilevich V.V., Isupova L.A., Kagyrmanova A.P., Kharina I.V., Zyuzin D.A., Noskov A.S. Highly effective water adsorbents based on aluminum oxide. Kinet. Catal. 2012. 53(5): 632. https://doi.org/10.1134/S0023158412050059
Islam M.A., Morton D.W., Johnson B.B., Pramanik B.K., Mainali B., Angove M.J. Metal ion and contaminant sorption onto aluminium oxide-based materials: a review and future research. J. Environ. Chem. Eng. 2018. 6(6): 6853. https://doi.org/10.1016/j.jece.2018.10.045
Mal'tseva T.V., Kudelko E.O., Belyakov V.N. Adsorption of Cu(II), Cd(II), Pb(II), Cr(VI) by double hydroxides on the basis of Al oxide and Zr, Sn, and Ti oxides. Russ. J. Phys. Chem. A. 2009. 83(13): 2336. https://doi.org/10.1134/S0036024409130263
Mal'tseva, T.V., Yatsenko, T.V., Kudelko, E.O., Belyakov V.N. The effect of introduction of manganese hydroxide and hydrated aluminum oxide on the pore structure and surface charge of Zr(IV), Ti(IV), and Sn(IV) oxyhydrates. Russ. J. Appl. Chem. 2011. 84: 756. https://doi.org/10.1134/S107042721105003X
Mal'tseva T.V., Pal'chik A.V., Kudelko E.O., Vasilyuk S.L., Kazdobin K.A. Impact of surface properties of hydrated compounds based on ZrO2 on the value of ionic conduction. J. Water Chem. Technol. 2015. 37(1): 18.https://doi.org/10.3103/S1063455X15010051
Dzyazko Y.S., Rozhdestvenska L.M., Palchik A.V. Ion-exchange properties and mobility of Cu2+ ions in zirconium hydrophosphate ion exchangers. Sep. Purif. Technol. 2005. 45(2): 141. https://doi.org/10.1016/j.seppur.2005.03.005
Pal'chik A.V., Dzyazko Yu.S., Rozhdestvenskaya L.M. Recovery of nickel ions from dilute solutions by electrodialysis combined with ion exchange. Russ. J. Appl. Chem. 2005. 75(3): 414. https://doi.org/10.1007/s11167-005-0307-y
Wu Y., Chen J., Liu Zh., Nab P., Zhang Zh. Removal of trace radioactive Cs+ by zirconium titanium phosphate: From bench-scale to pilot-scale. J. Environ. Chem. Eng. 2022. 10(4): 108073. https://doi.org/10.1016/j.jece.2022.108073
Amphlett B. Inorganic Ion Exchangers. (New York: Elsevier, 1964).
Wang X.-M., Li X.-Y., Shih, K. In situ embedment and growth of anhydrous and hydrated aluminum oxide particles on polyvinylidene fluoride (PVDF) membranes. J. Memb. Sci. 2011. 368(1-2): 134. https://doi.org/10.1016/j.memsci.2010.11.038
Saleh T.A., Gupta V.K. Synthesis and characterization of alumina nano-particles polyamide membrane with enhanced flux rejection performance. Sep. Purif. Technol. 2012. 89: 245. https://doi.org/10.1016/j.seppur.2012.01.039
Branchi M., Sgambetterra M., Pettiti I., Panero S., Navarra M.A. Functionalized Al2O3 particles as additives in proton-conducting polymer electrolyte membranes for fuel cell applications. Int. J. Hydrogen Energy. 2015. 40(42): 14757. https://doi.org/10.1016/j.ijhydene.2015.07.030
Yang C.-C., Chiu S.-J., Chien W.-C., Chiu S.-S. Quaternized poly(vinyl alcohol)/alumina composite polymer membranes for alkaline direct methanol fuel cells. J. Power Sources. 2010. 195(8): 2212. https://doi.org/10.1016/j.jpowsour.2009.10.091
Myronchuk V., Zmievskii Yu., Dzyazko Yu., Rozhdestvenska L., Zakharov V. Whey desalination using polymer and inorganic membranes: Operation conditions. Acta Periodica Technologica. 2018. 49: 103. https://doi.org/10.2298/APT1849103M
Dzyazko Yu., Rozhdestveskaya L., Zmievskii Yu., Volfkovich Yu., Sosenkin V., Nikolskaya N., Vasilyuk S., Myronchuk V., Belyakov V. Heterogeneous membranes modified with nanoparticles of inorganic ion-exchangers for whey demineralization. Materials Today: Proceedings. 2015. 2(6): 3864. https://doi.org/10.1016/j.matpr.2015.08.003
Myronchuk V.G., Dzyazko Yu.S., Zmievskii Yu.G., Ukrainets A.I. Organic-inorganic membranes for filtration of corn distillery. Acta Periodica Technologica. 2016. 47: 153. https://doi.org/10.2298/APT1647153M
Dzyazko Y.S., Rozhdestvenska L.M., Vasilyuk S.L., Kudelko K.O., Belyakov V.N. Composite membranes containing nanoparticles of inorganic ion exchangers for electrodialytic desalination of glycerol. Nanoscale Res. Lett. 2017. 12(1): 1. https://doi.org/10.1186/s11671-017-2208-4
Liu S., Tian J., Zhang W. Fabrication and application of nanoporous anodic aluminum oxide: a review. Nanotechnology. 2021. 32(22): 222001. https://doi.org/10.1088/1361-6528/abe25f
Poinern G.E.J., Ali N., Fawcett D. Progress in nano-engineered anodic aluminum oxide membrane development. Materials (Basel). 2011. 4(3): 487. https://doi.org/10.3390/ma4030487
Lee W., Park S.-J. Porous anodic aluminum oxide: anodization and templated synthesis of functional nanostructures. Chem. Rev. 2014. 114(15): 7487. https://doi.org/10.1021/cr500002z
Xia Z., Riester L., Sheldon B.W., Curtin W.A., Liang J., Yin A., Xu J.M. Mechanical properties of highly ordered nanoporous anodic alumina membranes. Rev. Adv. Mater. Sci. 2004. 6(2): 131.
Platschek B., Keilbach A., Bein T. Mesoporous structures confined in anodic alumina membranes. Adv. Mater. 2011. 23(21): 2395. https://doi.org/10.1002/adma.201002828
Yuan J.H., He F.Y., Sun D.C., Xia X.H. A Simple method for preparation of through-hole porous anodic alumina membrane. chemistry of materials. Chem. Mater. 2004. 16(10): 1841. https://doi.org/10.1021/cm049971u
Yuan J.H., Chen W., Hui R.J., Hu Y.L., Xia X.H. Mechanism of one-step voltage pulse detachment of porous anodic alumina membranes. Electrochim. Acta. 2006. 51(22): 4589. https://doi.org/10.1016/j.electacta.2005.12.044
Mardilovich P.P., Govyadinov A.N., Mukhurov N.I., Rzhevskii A.M., Paterson R. New and modified anodic alumina membranes Part I. Thermotreatment of anodic alumina membranes. J. Membr. Sci. 1995. 98(1-2): 131. https://doi.org/10.1016/0376-7388(94)00184-Z
Patel Y., Palevičius A., Naginevičius V., Liaudanskaite J., Janušas G. Aluminum oxide membrane as a functional element for filtering bioparticles in micro hydraulic devices. In: Frontiers in Ultrafast Optics: Biomedical, Scientific, and Industrial Applications XX. Proc. SPIE11270. 2020. P. 1127004. https://doi.org/10.1117/12.2541640
Osmanbeyoglu H., Hurb Tae Bong, Kim Hong Koo. Thin alumina nanoporous membranes for similar size biomolecule separation. J. Membr. Sci. 2009. 343: 1. https://doi.org/10.1016/j.memsci.2009.07.027
Attaluri A.C., Huang Z., Belwalkar A., Geertruyden W.V., Gao D., Misiolek W. Evaluation of nano-porous alumina membranes for hemodialysis application. ASAIO J. 2009. 55(3): 217. https://doi.org/10.1097/MAT.0b013e3181949924
Sharma A. Ph.D (Chem.) Thesis. (London, 2018).
Joung C.-K., Kim H.-N., Lim M.-C., Jeon T.-J., Kim H.-Y., Kim Y.-R. A nanoporous membrane-based impedimetric immunosensor for label-free detection of pathogenic bacteria in whole milk. Biosens. Bioelectron. 2013. 44: 10. https://doi.org/10.1016/j.bios.2013.01.024
Su T., He L., Mo R., Zhou C., Wang Z., Wan Y., Li C. A non-enzymatic uric acid sensor utilizing ion channels in the barrier layer of a porous anodic alumina membrane. Electrochem. Commun. 2018. 96: 113. https://doi.org/10.1016/j.elecom.2018.10.017
Vandekerkhove A., Negahdar L., Glas D. Synthesis and characterization of Ru-loaded anodized aluminum oxide for hydrogenation catalysis. ChemistryOpen. 2019. 8(4): 532. https://doi.org/10.1002/open.201900091
Liu C., Gillette EI., Chen X., Pearse A.J., Kozen A.C., Schroeder M.A., Gregorczyk K.E., Lee S.B., Rubloff G.W. An all-in-one nanopore battery array. Nat. Nanotechnol. 2014. 9: 1031. https://doi.org/10.1038/nnano.2014.247
Ahn Y., Park J., Shin D., Cho S., Park S.Y., Kim H., Kim Y.S. Enhanced electrochemical capabilities of lithium ion batteries by structurally ideal AAO separator. J. Mater. Chem. A. 2015. 3(20): 10715. https://doi.org/10.1039/C5TA01892G
Shi W., Shena Y., Gea D., Xue M., Cao H., Huanga S., Wangc J., Zhangc G., Zhangc F. Functionalized anodic aluminum oxide (AAO) membranes for affinity protein separation. J. Membr. Sci. 2008. 325(2): 801. https://doi.org/10.1016/j.memsci.2008.09.003
Hou P., Liu C., Shi C., Cheng, H. Carbon nanotubes prepared by anodic aluminum oxide template method. Chin. Sci. Bull. 2011. 57(2-3): 187. https://doi.org/10.1007/s11434-011-4892-2
Sui Y., Cui B., Guardián R., Acosta D., Martı́nez L., Perez R. Growth of carbon nanotubes and nanofibres in porous anodic alumina film. Carbon. 2002. 40(7): 1011. https://doi.org/10.1016/S0008-6223(01)00230-5
Yang S.M., Chen K.H., Yang Y.F. Synthesis of polyaniline nanotubes in the channels of anodic alumina membrane. Synthetic Metals. 2005. 152(1-3): 65. https://doi.org/10.1016/j.synthmet.2005.07.142
Wang D., Zhang L., Lee W., Knez M., Liu L. Novel three‐dimensional nanoporous alumina as a template for hierarchical TiO2 nanotube arrays. Small. 2013. 9(7): 1025. https://doi.org/10.1002/smll.201201784
Rozhdestvenka L.M., Kudelko K.O., Ogenko V.M., Menglei Ch. Membrane materials based on porous anodic aluminium oxide Ukr. Chem. J. 2020. 86(12): 67. https://doi.org/10.33609/2708-129X.86.12.2020.67-102
Kudelko K., Rozhdestvenskaya L., Ogenko V., Chmilenko V. Formation and characterisation of porous anodized aluminum oxide, synthesized electrochemically in the presence of graphene oxide. Appl. Nanosci. 2022. 12: 1967. https://doi.org/10.1007/s13204-022-02457-y
Li Z., Fan G., Tan Z., Guo Q., Xiong D., Su Y., Zhang D. Uniform dispersion of graphene oxide in aluminum powder by direct electrostatic adsorption for fabrication of graphene/aluminum composites. Nanotechnol. 2014. 25(32): 325601. https://doi.org/10.1088/0957-4484/25/32/325601
Ding R., Li W., Wang X., Gui T., Li B., Han P., Song L. A brief review of corrosion protective films and coatings based on graphene and graphene oxide. J. Alloys Compd. 2018. 764: 1039. https://doi.org/10.1016/j.jallcom.2018.06.133
Ivaništšev V., Fedorov M.V., Lynden-Bell R.M. Screening of Ion-Graphene Electrode Interactions by Ionic Liquids: The Effects of Liquid Structure. J. Phys. Chem. C. 2014. 118(11): 5841. https://doi.org/10.1021/jp4120783
Kong N., Liu J., Kong Q., Wang R., Barrow C.J., Yang W. Graphene modified gold electrode via π-π stacking interaction for analysis of Cu2+ and Pb2+. Sens. Actuators, B. 2013. 178: 426. https://doi.org/10.1016/j.snb.2013.01.009
Yang Y., Asiri A.M., Tang Z., Du D., Lin Y. Graphene based materials for biomedical applications. Mater. Today. 2013. 16(10): 365. https://doi.org/10.1016/j.mattod.2013.09.004
Perlova O.V., Ivanova I.S., Dzyazko Y.S., Danilov M.O., Rusetskii I.A., Kolbasov G.Ya. Sorption of U(VI) compounds on inorganic composites containing partially unzipped multiwalled carbon nanotubes. Him. Fiz. Tehnol. Poverhni. 2021. 12(1): 18. https://doi.org/10.15407/hftp12.01.018
Perlova O.V., Dzyazko Yu. S., Palchik A.V., Ivanova I.S., Perlova N.O., Danilov M.O., Rusetskii I.A., Kolbasov G.Ya., Dzyazko A.G. Composites based on zirconium dioxide and zirconium hydrophosphate containing graphene-like additions for removal of U(VI) compounds from water. J. Appl. Nanosci. 2020. 10: 4591. https://doi.org/10.1007/s13204-020-01313-1
Luo X., Wang C., Wang L., Deng F., Luo S., Tu X., Au C. Nanocomposites of graphene oxide-hydrated zirconium oxide for simultaneous removal of As(III) and As(V) from water. Chem. Eng. J. 2013. 220: 98. https://doi.org/10.1016/j.cej.2013.01.017
Rozhdestvenska L., Kudelko K., Ogenko V., Palchik O., Plisko T., Bildyukevich A, Zakharov V., Zmievskii Y., Vishnevskii O. Filtration membranes containing nanoparticles of hydrated zirconium oxide-graphene oxide. In: Springer Proceedings in Physics: Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications. 2020. 246: 757. https://doi.org/10.1007/978-3-030-51905-6_51
Wang X., Zhao Y., Tian E., Li J., Ren Y. Graphene oxide-based polymeric membranes for water treatment. Adv. Mater. Interfaces. 2018. 5(15): 1701427. https://doi.org/10.1002/admi.201701427
Ng L.Y., Chua H.S., Ng C.Y. Incorporation of graphene oxide-based nanocomposite in the polymeric membrane for water and wastewater treatment: A review on recent development. J. Environ. Chem. Eng. 2021. 9(5): 105994. https://doi.org/10.1016/j.jece.2021.105994
Ogenko V., Orysyk S., Kharkova L., Yanko O., Chen D. Synthesis and spectral characteristics of Cu(II), Ni(II) and Fe(III) nanosized complexes on the surface of carbon quantum dot. Ukr. Chem. J. 2021. 87(9): 3. https://doi.org/10.33609/2708-129X.87.09.2021.3-13
Sulka G.D. Highly ordered anodic porous alumina formation by self‐organized anodizing. (WILEY-VCH, 2008).
Goa J. A micro biuret method for protein d determination of total protein in cerebrospinal fluid. Scand. J. Clin. Lab. Invest. 1953. 5(3): 218. https://doi.org/10.3109/00365515309094189
Dzyazko Yu., Ogenko V. Polysaccharides: An efficient tool for fabrication of carbon nanomaterials. in: polysaccharides: properties and applications. (Wiley-Scrinever, Hoboken, Beverly, 2021). P. 337. https://doi.org/10.1002/9781119711414.ch16
Nielsch K., Choi J., Schwirn K., Wehrspohn R.B., Gösele U. Self-ordering regimes of porous alumina: the 10 porosity rule. Nano Lett. 2002. 2(7): 677. https://doi.org/10.1021/nl025537k
Barathi M., Krishna Kumar A.S., Kumar C.U., Rajesh N. Graphene oxide-aluminium oxyhydroxide interaction and its application for the effective adsorption of fluoride. RSC Adv. 2014. 4(96): 53711. https://doi.org/10.1039/C4RA10006A
Che Y., Sun Z., Zhan R., Wang S., Zhou S., Huang J. Effects of graphene oxide sheets-zirconia spheres nanohybrids on mechanical, thermal and tribological performances of epoxy composites. Ceram. Int. 2018. 44(15): 18067. https://doi.org/10.1016/j.ceramint.2018.07.010
Bogoyavlensky A.F. The mechanism of formation of anodic oxide film on aluminum. (Moscow: Mashinostroenie, 1964). [in Russian].
Garsia-Vergara S.J., Skeldon P., Thompson G.E., Habazaki H. Formation of porous anodic alumina in alkaline borate electrolyte. Thin Solid Films. 2007. 515(3): 5418. https://doi.org/10.1016/j.tsf.2007.01.013
Lee W., Ji R., Gösele U., Nielsch K. Fast fabrication of long-range ordered porous alumina membranes by hard anodization. Nat. Mater. 2006. 5: 741. https://doi.org/10.1038/nmat1717
Dzyazko Yu.S., Rozhdestvenskaya L.M., Vasilyuk S.L., Belyakov V.N., Kabay N., Yuksel M., Arar O., Yuksel U. Electro-deionization of Cr (VI)-containing solution. Part I: chromium transport through granulated inorganic ion-exchanger. Chem. Eng. Commun. 2008. 196(1-2): 3. https://doi.org/10.1080/00986440802303681
DOI: https://doi.org/10.15407/hftp14.02.237
Copyright (©) 2023 K. O. Kudelko, L. M. Rozhdestvenska, L. M. Ponomarova, V. M. Оgenko
This work is licensed under a Creative Commons Attribution 4.0 International License.