Chemistry, Physics and Technology of Surface, 2011, 2 (1), 61-75.

Influence of Phase Composition of Atmospheric Aerosols on the Interaction Kinetics with Volatile Impurities



V. I. Bogillo

Abstract


The influence of relative humidity of the air on the interaction kinetics of volatile impurities with components of atmospheric aerosols is described. The relations between uptake coefficients and relative humidity value are proposed to describe the experimental dependences for different systems. The kinetic "resistances" model was used to describe the stationary interaction kinetics of gas with nonvolatile reactant lying in the volume of spherical particle. The limiting cases for overall rate by the individual processes are studied. The expressions are derived for ratio of surface to volume reaction rates. The ratio increases as the size of the atmospheric particle drops.

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References


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