Professor Tetiana V. Kulyk

Tetiana Kulyk (Kulik)

Professor, Doctor of Science, Ph.D.

 

Chuiko Institute of Surface Chemistry

National Academy of Sciences of Ukraine,

17, General Naumov Str.

Kyiv-164, 03164, Ukraine,

Phone: +38 (044) 424 96 76, +38 (068) 119 07 49

Fax: +38 (044) 424 35 67

E-mail: tanyakulyk.isc.ms@gmail.com, tanyakulyk@i.ua

http://www.isc.gov.ua/index.php/en/institute-structure/scientific-departments?id=252

https://orcid.org/0000-0002-1740-0348

Scopus Author ID: 7006138489

 

Degree of Doctor of Science

2020     Doctor of Science in Physis and Chemistry of Surface, Chuiko Institute of Surface Chemistry of NASU (ISC), dissertation title: “Systematic relationships in the catalytic pyrolysis of natural compounds on the surface of nanosized oxides of groups III and IV elements”.

Degree of Ph.D.

2000     Ph.D. in Physis and Chemistry of Surface, Chuiko Institute of Surface Chemistry of NASU, dissertation title: «Mass spectrometry of carbohydrate fragments - terminal groups of receptors molecules in condensed state and in adsorbed state on the surface of ultrafine silica».

Specialist certification

2007     Senior Researcher in the Surface Physics and Chemistry

2021     Professor in Chemistry

Higher education qualification

1984     Chemistry, Taras Schevchenko National University, Kyiv, Ukraine, Department of Organic chemistry (chemistry of heterocyclic compounds).

 

Professional Appointments

2014-present       Head of the Laboratory "Kinetics and Mechanisms of Chemical Transformations on Solid Surfaces" (KinMechChemSurf), Chuiko Institute of Surface Chemistry of NASU, Kyiv, Ukraine

2004-2014  Senior Researcher, Head of the Biomolecules&Biopolymers Desorption Mass Spectrometry research group (since 2004), Chuiko Institute of Surface Chemistry of NASU, Kyiv, Ukraine

1988-2004  2001-2004 - Senior Researcher, 2000-2001 - Researcher, 1988-2000 - leading engineer, Chuiko Institute of Surface Chemistry of NASU, Kyiv, Ukraine

1984-1988  Engineer, Department of Acetylene Chemistry, Institute of Organic Chemistry of NASU, Kyiv

 

Research Interests

(i)      Pyrolysis; Catalysis; Physical Chemistry: Kinetics, Mechanisms, Surface chemistry, Physical organic chemistry.

(ii)     Investigating processes of heterogeneous catalytic pyrolysis of renewable biomass components for a development of green technologies of synthesis of biochemicals and biofuel.

(iii)    Use of TPD-MS and Linear Free Energy Relationships for Assessing the Reactivity of organic molecules, biomolecules and biopolymers on Nanooxides/Catalysts Surfaces.

 

Supervision: T.V. Borodavka, 2011, Ph.D.; L.R. Azizova, 2013, Ph.D.; O.O. Dudik, 2014, Ph.D.

Mentoring: ▪         Ph.D. Student Maria V. Pazo Cepeda fellowship from The University of Valladolid for conducting research by TPD MS at KinMechChemSurf Laboratory of ISC (Ph.D. 2019, The University of Valladolid, Spain); Postdoctoral fellows: N. Nastasiienko (2018 - present); Postbachelor fellows: A. Smykovs’ka (2011-12).

 

International collaborations:

  • Principal Investigator of the Project between Purdue University (Prof. J. Laskin - Principal Investigator from Purdue University) and Chuiko Institute of Surface Chemistry “Nanocatalyst-assisted pyrolysis for conversion of lignocellulose waste residues into sustainable biofuels using microwave treatment” FSA3-20-66700-0 from the U.S. Civilian Research & Development Foundation (CRDF Global) with funding from the United States Department of State, 2020-2021.
  • Project Manager of the Project between Leibniz Institute of Surface Engineering (IOM, Germany) and Chuiko Institute of Surface Chemistry “Next generation solid acid fuel cells and electrolyzers for a sustainable energy future” (Science and Technology Center in Ukraine (P 707, STCU)), 2018.
  • Team Leader of the Project between Stockholm University and Chuiko Institute of Surface Chemistry “Development of green nanotechnologies for catalytic pyrolysis of biomass” (Swedish Research Council under contract 348-2014-4250), 2016-2018.
  • Principal Investigator of the Project “Pyrolysis with the use of nanocatalysts MexOy/SiO2 the way to get second-generation biofuels via processing of fatty acids, triglycerides and renewable plant biomass” UKC2-7072-KV-12 from the U.S. Civilian Research & Development Foundation (CRDF Global) with funding from the United States Department of State, Northwest National Laboratory (PNNL), U.S. Department of Energy, Richland, Washington, USA, 2013-2015.
  • 2008-12 Hybrid Nanocomposites and their Biomedical Applications, FP7-PEOPLE-IRSES-2008 (UK, Poland, Greece, Hungary, Ukraine).
  • 2008-11 STCU (Science and Technology Center in Ukraine) Grant 3832 “Modernization of processing technology for pharmaceutical preparation Silics.”
  • Innocentive #4039381, “Pyrolysis of Cellulose”, March 28, 2007.
  • 2004-06 STCU (Science and Technology Center in Ukraine). Grant 3103 “High-dispersed compositions: the way to optimization of reproductive cell media”.

 

Honours, Awards, Fellowships:

  • research scholarship for Professor within Visby Programme [03804/2016, the Swedish Institute], the Project “Testing of the important catalytic reactions for green pyrolytic conversion of algae biomass to biofuels and chemicals”, Stockholm University, 2016.
  • the EMSL User Project #48581 "Mass-selected Ion Deposition and Surface Characterization Techniques for Evaluation of Nanocatalytic Conversion of Biomass Components in Biofuels Production" (Environmental Molecular Sciences Laboratory (EMSL), U.S. Department of Energy, Richland, Washington, USA, 2014).

 

Last presentations:

2023           Cardiff Catalysis Institute Conference, 11-12th January 2023. T. Kulik, B. Palianytsia, Kinetics and mechanisms of catalytic pyrolysis of biomass: linear free energy relationships, isotope effect and desorption mass spectrometry. Plenary lecture. Invited Oral presentation.

2022           20th International Zeolite Conference, Valencia, Spain, 3-8 July, 2022.

2018           CAT 2018, 2nd Global Conference of Catalysis, Chemical Engineering&Technology, Rome, Italy.

2018           CIENCE@FELs, Stockholm, Sweden.

2017           International Symposium on Green Chemistry (ISGC), La Rochelle, France.

2017           BIT’s 5th Annual Conference of AnalytiX, Fukuoka, Japan.

2016           21st International Mass Spectrometry. Conference (21st IMSC). Toronto, Canada.

2013           International Congress on Energy Efficiency and Energy Related Materials (ENEFM), Antalya, Turkey.

2012           4th German-Ukrainian Symposium “Physics and chemistry of nanostructures and nanobiotechnology”, Ilmenau, Germany

2012           Advanced Macromolecular Systems Across the Length Scales Symposium, Lake Balaton, Hungary

2012           10th Conference on Colloid Chemistry, Budapest, Hungary, 2012.

2010           XIІ Polish-Ukrainian Symposium, Kielce-Ameliowka, Poland, 2010.

2009           The E-MRS Spring Meeting, Strasbourg, 2009.

2009           18th International Mass-Spectrometry Conference (IMSC), Bremen, Germany.

 

Selected Publications

>90 publications, h-index=16 (Scopus), h-index=17 (Google Scholar), i10-index=27:

 

  1. T.V. Kulik, Use of TPD-MS and Linear Free Energy Relationships for Assessing the Reactivity of Aliphatic Carboxylic Acids on a Silica Surface. J. Phys. Chem. C, 2012, 116, 570–580. https://doi.org/10.1021/jp204266c
  2. Kulik, T.; Palianytsia, B.; Larsson, M. Catalytic Pyrolysis of Aliphatic Carboxylic Acids into Symmetric Ketones over Ceria-Based Catalysts: Kinetics, Isotope Effect and Mechanism. Catalysts 2020, 10, 179, 1-21. This article belongs to the section “Biomass Catalysis” and to the Special Issue “Catalysis for the Production of Sustainable Fuels and Chemicals”. Open access. https://doi.org/10.3390/catal10020179
  3. Azizova, L.R.*, Kulik, T.V.*, Palianytsia, B.B., Ilchenko, M.M., Telbiz, G.M., Balu, A.M., Tarnavskiy, S., Luque, R., Roldan, A. and Kartel, M.T., 2023. The Role of Surface Complexes in Ketene Formation from Fatty Acids via Pyrolysis over Silica: from Platform Molecules to Waste Biomass. Journal of the American Chemical Society, 145(49), 26592-26610. (IF= 15) DOI: 10.1021/jacs.3c06966
  4. Nastasiienko, N., Kulik, T., Palianytsia, B., M Larsson, M Kartel, Microwave-assisted catalytic pyrolysis of ferulic acid, as a lignin model compound. J Therm Anal Calorim 148, 5485–5492 (2023). https://doi.org/10.1007/s10973-023-12087-3 (IF= 4.755)
  5. Pazo-Cepeda, M. V., Nastasiienko, N. S., Kulik, T. V., Palianytsia, B. B., Alonso, E., & Aspromonte, S. G. (2023). Adsorption and thermal transformation of lignin model compound (ferulic acid) over HY zeolite surface studied by temperature programmed desorption mass-spectrometry, FTIR and UV–Vis spectroscopy. Microporous and Mesoporous Materials, 348, 112394. Microporous and Mesoporous Materials, 348, 2023, 112394. https://doi.org/10.1016/j.micromeso.2022.112394 (IF 5.876)
  6. V. Halysh, J.M. Romero-García, A.M. Vidal, T. Kulik, B. Palianytsia, M. García, E. Castro. Apricot Seed Shells and Walnut Shells as Unconventional Sugars and Lignin Sources. Molecules, 28 (3), 2023, 1455. Open access. https://doi.org/10.3390/molecules28031455 (IF 4.927)
  7. T. Len, V. Bressia, A.M. Balu, T. Kulik, O. Korchuganova, B. Palianytsia, C. Espro, R. Luque. Thermokinetics of production of biochar from crop residues: an overview. (Tutorial Review) Green Chemistry, 2022, 24, 7801-7817. 2022. DOI: 10.1039/D2GC02631G (IF 11.034)
  8. L. Azizova, D. Morgan, J. Rowlands, E. Brousseau, T. Kulik, B. Palianytsia, J.P. Mansell, J. Birchall, T. Wilkinson, A. Sloan, W.N. Ayre. Parameters controlling octadecyl phosphonic acid self-assembled monolayers on titanium dioxide for anti-fouling biomedical applications. Applied Surface Science. 2022, Volume 604, 154462. https://doi.org/10.1016/j.apsusc.2022.154462 (IF 7.392)
  9. Halysh, V., Skiba, M., Nesterenko, A., Kulik, T., & Palianytsia, B. Structural characterization of by-product lignins from organosolv rapeseed straw pulping and their application as biosorbents. Journal of Polymer Research, 2022, 29(12), 1-13. https://doi.org/10.1007/s10965-022-03368-w   ІF=3,061
  10. Kulik, T. Systematic relationships in the catalytic pyrolysis of natural compounds on the surface of nanosized oxides of groups III and IV elements. – Manuscript, 426 p. Thesis for a Doctor of Sciences degree in speciality 01.04.18 – Physics and Chemistry of Surface. – Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine. – Kyiv, 2020.
  11. Kulik, T.; Nastasiienko, N.; Palianytsia, B.; Ilchenko, M.; Larsson, M. Catalytic Pyrolysis of Lignin Model Compound (Ferulic Acid) over Alumina: Surface Complexes, Kinetics, and Mechanisms. Catalysts 2021, 11, 1508, 1-24. (This article belongs to the Special Issue Catalytic Fast Pyrolysis for Biofuels and Sustainable Chemicals) https://doi.org/10.3390/catal11121508
  12. Nastasiienko, N.; Kulik, T.; Palianytsia, B.; Laskin, J.; Cherniavska, T.; Kartel, M.; Larsson, M. Catalytic Pyrolysis of Lignin Model Compounds (Pyrocatechol, Guaiacol, Vanillic and Ferulic Acids) over Nanoceria Catalyst for Biomass Conversion. Appl. Sci. 2021, 11, 7205. https://doi.org/10.3390/app11167205
  13. LR Azizova, TV Kulik, BB Palianytsia, GM Telbiz, MT Kartel, Secondary structure of muramyl dipeptide glycoside in pristine state and immobilized on nanosilica surface. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 631, 127724. https://doi.org/10.1016/j.colsurfa.2021.127724
  14. Nastasiienko, N.; Kulik, T.; Palianytsia, B.; Larsson, M.; Cherniavska, T.; Kartel, M. Decarboxylation of p-Coumaric Acid during Pyrolysis on the Nanoceria Surface. Colloids Interfaces 2021, 5, 48. https://doi.org/10.3390/colloids5040048
  15. N. Nastasiienko, B. Palianytsia, M. Kartel, M. Larsson, T. Kulik, Thermal Transformation of Caffeic Acid on the Nanoceria Surface Studied by Temperature Programmed Desorption Mass-Spectrometry, Thermogravimetric Analysis and FT–IR Spectroscopy. Colloids and Interfaces, 2019, 3 (1), 34, 1-14. Open access. https://doi.org/10.3390/colloids3010034
  16. Yefremova, S., Zharmenov, A., Sukharnikov, Y., Bunchuk, L., Kablanbekov, A., Anarbekov, K., Kulik, T., Nikolaichuk, A., Palianytsia, B., Rice Husk Hydrolytic Lignin Transformation in Carbonization Process. Molecules, 2019. 24(17), p.3075. Open access. https://doi.org/10.3390/molecules24173075
  17. K.Kulyk B.Palianytsia, J.D.Alexander, L.Azizova, M.Borysenko, M.Kartel, M.Larsson, T.Kulik. Kinetics of valeric acid ketonization and ketenization in catalytic pyrolysis on nanosized SiO2, γ-Al2O3, CeO2/SiO2, Al2O3/SiO2 and TiO2/SiO2. ChemPhysChem, 18, 2017. https://doi.org/10.1002/cphc.201601370
  18. T.V. Kulik, N.O. Lipkovska, V.M. Barvinchenko, B.B. Palyanytsya, O.A. Kazakova, O.O. Dudik, A. Menyhárd, K. László, Thermal transformation of bioactive caffeic acid on fumed silica seen by UV-Vis spectroscopy, thermogravimetric analysis, temperature programmed desorption mass spectrometry and quantum chemical methods, J. Colloid Interface Sci., 470, 2016, 132–141. https://doi.org/10.1016/j.jcis.2016.02.039
  19.  K. Kulyk, H. Zettergren, M. Gatchell, J.D. Alexander, M. Borysenko, B. Palianytsia, M. Larsson, T. Kulik, Dimethylsilanone Generation from Pyrolysis of Polysiloxanes Filled with Nanosized Silica and Ceria/Silica. ChemPlusChem, 2016, 81, 1003-1013. https://doi.org/10.1002/cplu.201600229
  20.  K.Kulyk, M. Borysenko, T. Kulik, L. Mikhalovska, J.D. Alexander, B. Palyanytsya, Chemisorption and thermally induced transformations of polydimethylsiloxane on the surface of nanoscale silica and ceria/silica. Polymer Degradation and Stability, 2015, 120, 203-211. https://doi.org/10.1016/j.polymdegradstab.2015.07.004
  21. L.R. Azizova, T.V. Kulik, B.B. Palyanytsya, N.A. Lipkovska. Thermal and hydrolytic stability of grafted ester groups of carboxylic acids on the silica surface, J. Therm. Anal. Calorim., 2015, 122, P. 517-523. https://doi.org/10.1007/s10973-015-4828-1
  22. T.V. Podust, T.V. Kulik, B.B. Palyanytsya, V.M. Gun'ko, A. Toth, L. Mikhalovska, A. Menyhard, K. Laszlo “Chitosan-nanosilicas hybrid materials: preparation and properties”, J. Applied Surface Sci., 2014, 320, 563–569. https://doi.org/10.1016/j.apsusc.2014.09.038
  23. L.R. Azizova, T.V. Kulik, B.B. Palyanytsya, A.E. Zemlyakov, V.N. Tsikalova, V.Ya. Chirva, Investigation of chemical transformations of thiophenylglycoside of muramyl dipeptide on the fumed silica surface using TPD-MS, FTIR spectroscopy and ES IT MS, Nanoscale Res. Lett., 2014, 9, 234-243. Open access. https://doi.org/10.1186/1556-276X-9-234
  24. B.B.Palianytsia, T.V. Kulik, O.O.Dudik, O.L.Toncha, T.V. Cherniavska, “Study of the thermal decomposition of some components of biomass by desorption mass spectrometry”, International Congress on Energy Efficiency and Energy Related Materials (ENEFM 2013), Series: Springer Proceedings in Physics, Vol. 155, Oral, A., Bahsi, Z.B., Ozer, M. (Eds.), 2014, XIV, 19-25. https://doi.org/10.1007/978-3-319-05521-3_3
  25. T.V. Kulik, V.N. Barvinchenko, B. B. Palyanytsya, N.A. Lipkovska, O.O.Dudik, “Thermal transformations of biologically active derivatives of cinnamic acid by TPD MS investigation”, J. Anal. Appl. Pyrolysis, 2011, 90, 219-223. https://doi.org/10.1016/j.jaap.2010.12.012
  26. Kulik, T.V., Dudik, O.A., Palyanitsa, B.B., Tarnavskii, S.S., Toth, A., Menihard, A. And Laszlo, K., 2011. Kinetics and Mechanism of the Deamination of Primary Aliphatic Amines on the Silica Surface. Theoretical and Experimental Chemistry,47(3), P.176. https://doi.org/10.1007/s11237-011-9200-3
  27. K.S.Kulyk, V.V.Ishchenko, B.B.Palyanytsya, V.P.Khylya, M.V.Borysenko, T.V.Kulyk A TPD-MS study of the interaction of coumarins and their heterocyclic derivatives with a surface of fumed silica and nanosized oxides CeO2/SiO2, TiO2/SiO2, Al2O3/SiO2, Journal of Mass Spectrometry, 2010, 45, 750-761. https://doi.org/10.1002/jms.1765
  28. T.V.Kulik, L.R.Azizova, B.B.Palyanytsya, A.E.Zemlyakov, V.N.Tsikalova “Mass spectrometric investigation of synthetic glycoside of muramyl dipeptide immobilized on fumed silica surface “ Materials Science and Engineering B, 2010, 169, 114–118. https://doi.org/10.1016/j.mseb.2009.12.003
  29. T.V. Kulik, N.N. Vlasova, B.B. Palyanytsya, O.V. Markitan, L.P. Golovkova, “Spectroscopic study of biogenic amine complexes formed at fumed silica surface”, J. Colloid Interface Sci., 2010 351, 515–522. https://doi.org/10.1016/j.jcis.2010.07.060
  30. T.V. Borodavka, T.V. Kulik, B.B. Palyanytsya “Application of temperature programmed desorption mass spectrometry for the determination of the deacetylation degree of chitosan”, Journal of Analytical Chemistry, 2010, Vol. 65, No.13, 1377-1381. https://doi.org/10.1134/S1061934810130113
  31. T.V. Kulik, N.A. Lipkovska, V.N. Barvinchenko, B.B. Palyanytsya, O.A. Kazakova, O.A. Dovbiy, V.K. Pogorelyi. Interactions between bioactive ferulic acid and fumed silica by UV-VIS spectroscopy, FT-IR, TPD MS investigation and quantum chemical methods. J. Colloid Interface Sci., 2009, 339, 60-68. https://doi.org/10.1016/j.jcis.2009.07.055
  32. Kulik TV, Palyanytsya BB, Borodavka TV, Borysenko MV Supramolecular structures of chitosan on the surface of fumed silica. In Nanomaterials and Supramolecular Structures, A.P. Shpak, P.P. Gorbyk (Eds), 2009, Springer, Dordrecht. 259-268. https://doi.org/10.1007/978-90-481-2309-4_21
  33. Gun'ko, V.M., Mironyuk, I.F., Zarko, V.I., Voronin, E.F., Turov, V.V., Pakhlov, E.M., Goncharuk, E.V., Nychiporuk, Y.M., Vlasova, N.N., Gorbik, P.P. and Mishchuk, O.A., A.A.Chuiko, T.V.Kulik, B.B.Palyanytsya, S.V.Pakhovchishin, J.Skubiszewska-Zięba, W.Janusz, A.V.Turov, R.Leboda 2005. Morphology and surface properties of fumed silicas. Journal of colloid and interface science, 289(2), 427-445. https://doi.org/10.1016/j.jcis.2005.05.051

  

APPENDIX

Participation in international grants

 

  1. 1.     Project Manager of the Project “Nanocatalyst-assisted pyrolysis for conversion of lignocellulose waste residues into sustainable biofuels using microwave treatment” FSA3-20-66700-0 from the U.S. Civilian Research & Development Foundation (CRDF Global) with funding from the United States Department of State, 2020-2021.
  2. Project Manager of the Project “Next generation solid acid fuel cells and electrolyzers for a sustainable energy future” (Science and Technology Center in Ukraine (P 707, STCU)), 2018.
  3. Team Leader of the Project between Stockholm University and Chuiko Institute of Surface Chemistry “Development of green nanotechnologies for catalytic pyrolysis of biomass” (Swedish Research Council under contract 348-2014-4250), 2016-2018.
  4. 4.     Project Manager of the Project “Pyrolysis with the use of nanocatalysts MexOy/SiO2 the way to get second-generation biofuels via processing of fatty acids, triglycerides and renewable plant biomass” UKC2-7072-KV-12 from the U.S. Civilian Research & Development Foundation (CRDF Global) with funding from the United States Department of State, 2013-2015.
  5. the Swedish Institute for research scholarship for professor within Visby Programme [03804/2016], the Project “Testing of the important catalytic reactions for green pyrolytic conversion of algae biomass to biofuels and chemicals”, 2016.
  6. Project Manager the EMSL User Project #48581 "Mass-selected Ion Deposition and Surface Characterization Techniques for Evaluation of Nanocatalytic Conversion of Biomass Components in Biofuels Production" (Northwest National Laboratory (PNNL), Richland, Washington, USA, 2014.

 

  • 2008-12 Hybrid Nanocomposites and their Biomedical Applications, FP7-PEOPLE-IRSES-2008 (UK, Poland, Greece, Hungary, Ukraine).
  • 2008-11 STCU (Science and Technology Center in Ukraine) Grant 3832 “Modernization of processing technology for pharmaceutical preparation Silics.”
  • Innocentive 4039381, “Pyrolysis of Cellulose”, March 28, 2007.
  • 2004-06 STCU (Science and Technology Center in Ukraine). Grant 3103 “High-dispersed compositions: the way to optimization of reproductive cell media”.

  

Participation in Ukrainian grants and programs:

 

NAS of Ukraine Program “New functional substances and materials of chemical production” (2017-2021, №15-2017; №04-2019), responsible executor.