Constructing the Models Describing Protolytic Equilibria on Aminoxerogel Surface

Authors

  • A. Yu. Baraban Karazin Kharkiv National University
  • I. V. Khristenko Karazin Kharkiv National University
  • O. S. Tkachenko Karazin Kharkiv National University
  • R. V. Sukhov Karazin Kharkiv National University
  • O. I. Yurchenko Karazin Kharkiv National University
  • Yu. V. Kholin Karazin Kharkiv National University

Abstract

On the base of probing the aminoxerogel surface by H+ ions the models have been constructed for interpretation of peculiarities of reactions occurring on the surface. The model of energetic heterogeneity postulates the presence of stoichiometrically identical sorption centers having different affinity to Н+ ions. The model of polydentate binding assumes that affinity of sorption centers to the probe is dependent on the degree of occupation of sorption centers. The model of chemical reactions describes the non-ideal nature of binding Н+ ions in terms of reactions supplementing the protonation of basic sorption centers. All tested models describe the experimental data properly, the model of polydentate binding provides the most meaningful information about features of protonation equilibria.

References

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How to Cite

(1)
Baraban, A. Y.; Khristenko, I. V.; Tkachenko, O. S.; Sukhov, R. V.; Yurchenko, O. I.; Kholin, Y. V. Constructing the Models Describing Protolytic Equilibria on Aminoxerogel Surface. Him. Fiz. Tehnol. Poverhni 2012, 3, 45-52.

Issue

Vol. 3 No. 1 (2012): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni

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Articles

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