Sorption of Heteropoly Acids on Cellulose Sorbents

Authors

  • O. V. Zui Dumansky Institute of Colloid Chemistry and Water Chemistry
  • V. N. Zaitsev Taras Shevchenko National University of Kyiv
  • S. A. Alekseev Taras Shevchenko National University of Kyiv
  • V. V. Trachevsky Kurdyumov Institute of Metallophysics of National Academy of Sciences of Ukraine

Abstract

Sorption of heteropoly acids on the surfaces of cellulose and diethylaminoethylcellulose with molybdovanadophosphoric acid as an example has been studied by UV-VIS, infrared, and MAS-NMR spectroscopy. It has been shown that sorption of heteropoly acid on diethylaminoethylcellulose is substantially higher than that on ordinary cellulose. The mechanism of sorption includes combination of Coulomb and hydrophobic interactions. A scheme of heteropoly acids immobilization has been proposed based on ion exchange on cellulose surface.

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(1)
Zui, O. V.; Zaitsev, V. N.; Alekseev, S. A.; Trachevsky, V. V. Sorption of Heteropoly Acids on Cellulose Sorbents. Him. Fiz. Tehnol. Poverhni 2012, 3, 66-73.

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Vol. 3 No. 1 (2012): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni

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