Hong-Ou-Mandel quantum effect on “polymer - multiwall cnt” composites
Abstract
The possibilities to enhance the properties of nanostructured surfaces are evaluated on “polymer-multiwall carbon nanotube” composites. Influence of sp3 hybridization bonds is investigated in composites derived from polypropylene, polyamide-6, polyamide-12 and polyvinyl chloride after adding CNTs to polymers. IR absorption of “polymer-CNTs” films exceeds that of polymer by 10-103 times in the entire measured spectral range. In addition, two-polar IR absorption are measured on composites with negative components at spectral positions of “D-band” and “2D-band” of sp3 hybridization. In this case, the greater oscillation amplitudes of C-C, CH2 and CH3 bonds correspond to a higher absorption at the vibration frequencies γω(CН) and γω(CH2). Two-polar oscillations of absorption with a negative component in the spectral band ranges “D” and “2D” of sp3 hybridization in nanotubes have been measured for the composites. Frequencies of 2D-band correspond to the second order frequencies of D-band. The intensity of 2D band increases with an increase in the concentration of defects. The absorption of light increases when the frequencies of local oscillations of surface bonds in carbon nanotubes correspond to the frequencies of slotted modes along the boundary of the “nanotube polymer” (surface polaritons). Two-polar oscillations have an ultra-small half width 0.4–0.6 cm–1, which indicates a strong interaction of surface polaritons with photons. Vertically polarized light along carbon nanotubes and horizontally polarized light of D and 2D bands resulted in light beams splitting, two-photon interference and realization of the quantum Hong-Ou-Mandel effect.References
1. Karachevtseva L.A., Lytvynenko O.O., Onyshchenko V.F., Strelchuk V.V., Boyko V.A. Exciton-polaritons in 2D macroporous silicon structures with nano-coatings. Him. Fiz. Tehnol. Poverhni. 2020. 10(4): 9. https://doi.org/10.15407/hftp11.04.445
2. Karachevtseva L.A., Kartel M.T., Lytvynenko O.O. 1D and 2D polaritons in macroporous silicon structures with nano-coatings. Him. Fiz. Tehnol. Poverhni. 2021. 11(1): 9. https://doi.org/10.15407/hftp12.01.009
3. Treacy M., Ebbesen T., Gibson J. Exceptionally high Young's modulus observed for individual carbon nanotubes. Nature. 1996. 381: 678. https://doi.org/10.1038/381678a0
4. Bauhofer W., Kovacs J. A review and analysis of electrical percolation in carbon nanotube polymer composites. Comp. Sci. Technol. 2009. 69(10): 1486. https://doi.org/10.1016/j.compscitech.2008.06.018
5. Lacerda L., Bianco A., Prato M., Kostarelos M. Carbon nanotubes as nanomedicines: from toxicology to pharmacology. Adv. Drug Delivery Rev. 2006. 58(14): 1460. https://doi.org/10.1016/j.addr.2006.09.015
6. Wilder W., Venema L., Rinzler A., Smalley, R., Dekker C. Electronic structure of atomically resolved carbon nanotubes. Nature. 1998. 391: 59. https://doi.org/10.1038/34139
7. Fan S., Chapline M., Franklin N., Tombler T., Cassell A., Dai H. Self-oriented regular arrays of carbon nanotubes and their field emission properties. Science. 1999. 283(5401): 512. https://doi.org/10.1126/science.283.5401.512
8. Wei B., Vajtai R., Ajayan P. Reliability and current carrying capacity of carbon nanotubes. Appl. Phys. Lett. 2001. 79(8): 1172. https://doi.org/10.1063/1.1396632
9. Kompan M., Aksyanov I. Near-UV narrow-band luminescence of polyethylene and polytetrafluoroethylene. Phys. Solid State. 2009. 51(5): 1083. https://doi.org/10.1134/S1063783409050291
10. Karachevtseva L., Kartel M., Lytvynenko O., Onyshchenko V., Parshyn K., Stronska O. Polymer-nanoparticle coatings on macroporous silicon matrix. Adv. Mater. Lett. 2017. 8(4): 336. https://doi.org/10.5185/amlett.2017.1412
11. Thostenson E., Ren Z., Chou T-W. Advances in the Science and Technology of Carbon Nanotubes and their Composites: A Review. Compos. Sci. Technol. 2001. 61(13): 1899. https://doi.org/10.1016/S0266-3538(01)00094-X
12. Awasthi K., Srivastava A., Srivastava O. Synthesis of Carbon Nanotubes. J. Nanosci. Nanotechnol. 2005. 5(10): 1616. https://doi.org/10.1166/jnn.2005.407
13. Krimm S. Infrared Spectra of High Polymers. Fcrtschr. Hochpolym.-Forsch. 1960. 2: 51. https://doi.org/10.1007/BF02283926
14. Miyake A. Infrared spectra and crystal structures of polyamides. J. Polym. Sci. 1960. 44(143): 223. https://doi.org/10.1002/pol.1960.1204414319
15. Onyshchenko V., Karachevtseva L. Conductivity and photoconductivity of two-dimensional macroporous silicon structures. Ukr. J. Phys. 2013. 58(9): 846. https://doi.org/10.15407/ujpe58.09.0846
16. Resanova N., Kartel M., Sementsov Yu., Prikhod'ko G., Melnik I., Tsebrenko M. Rheological Properties of Molten Mixtures of Polypropylene/Copolyamide/Carbon Nanotubes. Him. Fiz. Tehnol. Poverhni. 2011. 2(4): 451.
17. Gerardi G.J., Poindexter E.H., Caplan P.J., Jonhson N.M. Interface traps and Pb centers in oxidized (100) silicon wafers. Appl. Phys. Lett. 1986. 49(6): 348. https://doi.org/10.1063/1.97611
18. Vinogradov E.A., Zhizhin G.N., Yakovlev V.A. Resonance between dipole oscillations of atoms and interference modes in crystalline films. J. Exp. Theor. Phys. 1979. 50: 486.
19. Vinogradov E.A. Semiconductor microcavity polaritons. Physics-Uspekhi. 2002. 45(12): 1213. https://doi.org/10.1070/PU2002v045n12ABEH001189
20. Ou Z., Hong C., Mandel L. Relation between input and output states for a beam splitter. Opt. Commun. 1987. 63(2): 118. https://doi.org/10.1016/0030-4018(87)90271-9
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