Написати автору Комплекси кавової кислоти на поверхні оксиду алюмінію: ІЧ спектроскопія, TПД МС та DFT розрахунки
DOI: https://doi.org/10.15407/hftp15.03.429
Анотація
Кавова кислота є фенольною природною біологічно активною сполукою з вираженими антиоксидантними та антимікробними властивостями, яка має великий потенціал застосування в медицині і косметології, а також може використовуватися для отримання ряду інших корисних хімікатів. Тому дослідження, спрямовані на вдосконалення технологій вилучення кавової кислоти з рослинної сировини, а також її переробки, є актуальними. В нашій роботі вивчалися комплекси кавової кислоти з нанорозмірним Al2O3, який зазвичай застосовують в різних технологіях конверсії рослинної біомаси. Структуру та тип утворених комплексів СА досліджено за допомогою ІЧ-спектроскопії, температурно-програмованої десорбційної мас-спектрометрії (ТПД МС) та квантовохімічних методів. Аналіз отриманих ІЧ-спектрів свідчить, що СА може взаємодіяти з нанорозмірним оксидом алюмінію як карбоксильною так і фенольними групами. На основі розрахованих значень Dν встановлено, що карбоксилатні комплекси СА на поверхні Al2O3 можуть мати бідентатну та монодентатну структури. Аналіз мас-спектрометричних даних дозволив ідентифікувати сполуки 4-вінілкатехолу, пірокатехолу та фенолу, які є продуктами розкладу утворених карбоксилатних та фенольних комплексів. Виявлено, що на поверхні досліджених зразків СА/Al2O3 переважають хелатні комплекси СА, які утворюються за участі обох ОН-груп ароматичного кільця.
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DOI: https://doi.org/10.15407/hftp15.03.429
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