Comparative <sup>13</sup>C NMR Spectroscopy of Lignocellulose Sorbents

Authors

  • M. T. Kartel Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • A. A. Nikolaichuk Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine

Abstract

The composition and structure of initial and modified lignocellulose materials have been investigated by 13C NMR spectroscopy. Changes in functional structure and composition of the samples have been found to arise due to modifying as a result of chemical transformations and hemicelluloses removing. Sorption properties of lignocellulose composites have been studied in relation to heavy metals. They have been found to depend on changes in the composition and functional structure of the materials.

References

Fernandez-Bolanos J., Felizon B., Herediat A., et al. Characterization of the lignin obtained by alkaline delignification and of the cellulose residue from steam-exploded olive stones // Bioresour. Technol. – 1999. – V. 68, N 2. – P. 121–132.

Pat. 76835 Ukraine, Int. Cl. A61K 36/87 Method of obtaining lignin-containing enterosorbents (variants) / V.O. Denisovych, A.A. Nikolaychuk, L.A. Kupchik, M.T. Kartel – Appl. No. 20040907527, Filed 15.09.2004, Publ. 15.09.2006. – 8 p. (in Ukrainian).

Semenkova G.G., Provotorov V.M., Velikaia O.V. The correction of the imbalance in the proteinase-inhibitor system of patients with protracted pneumonia with the enterosorbent polifepan // Klinicheskaya medi­tsina. – 1995. – V. 73, N 1. – Р. 48–50. (in Russian).

Karmanov A.P. Monakov Yu.B. The structure of lignin macromolecules // Polym. Sci. B. – 1996. – V 38, N 9–10. – Р. 384–394.

Li M.-F., Fan Y.-M., Xu F. et al. Cold sodium hydroxide/urea based pretreatment of bamboo for bioethanol production: Characterization of the cellulose rich fraction. // Ind. Crops Prod. – 2010. – V. 32, N 3. – P. 551–559.

Zhao H., Kwak J.H., Zhang Z.C. et al., Studying cellulose fiber structure by SEM, XRD, NMR and acid hydrolysis // Carbohydr. Polym. – 2007. – V. 68, N 2. – P. 235–241.

Nikolaichuk A.A., Kartel N.T., Kupchik L.A., Denisovich V.A. Synthesis and properties of biosorbents obtained from cellulose-lignin vegetative raw materials – wastes of agricultural complex // Sorbcionnye i hromatograficheskie processy. – 2007. – V. 1, N 3. – P. 489–498. (in Russian).

Downloads

How to Cite

(1)
Kartel, M. T.; Nikolaichuk, A. A. Comparative <sup>13< Sup>C NMR Spectroscopy of Lignocellulose Sorbents. Him. Fiz. Tehnol. Poverhni 2011, 2, 81-85.

Issue

Vol. 2 No. 1 (2011): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni

Section

Articles

License

  1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
  2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
  3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.