Chemistry, Physics and Technology of Surface, 2016, 7 (1), 20-30.

Investigation of the local environment of aminodiphosphonic acid covalently immobilized on silica surface by XPS and solid-state 31P NMR



DOI: https://doi.org/10.15407/hftp07.01.020

L. S. Kostenko, A. S. Andreev, J. Fraissard, S. A. Alekseev, V. N. Zaitsev

Abstract


The samples of silicas with covalently-immobilized aminodiphosphonic acid (SiO2–АDPA) have been characterized by the XPS and solid state 31P NMR spectroscopy. The samples were synthesized via Kabachnik-Fields reaction from aminopropyl silica gel, H3PO3 and formaldehyde, and have different concentrations (0.33–1.67 mmol/m2) of grafted groups and different yield (59–86%). It is demonstrated that chemical shift of the lines and number of resonance lines in the 31P NMR spectra of SiO2–АDPA depends on both the concentration of bonded groups and the yield. This difference was interpreted as a result of heterogeneity in the local environment of SiO2–АDPA surface.

Keywords


chemically modified silica; aminodiphosphonic acid; grafted groups; local heterogeneity; solid state NMR; XPS

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References


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DOI: https://doi.org/10.15407/hftp07.01.020

Copyright (©) 2016 L. S. Kostenko, A. S. Andreev, J. Fraissard, S. A. Alekseev, V. N. Zaitsev

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