Hydrothermal Modification of Vanadium-Molybdenym Oxide Catalysts for Oxidative Dehydrogenation of Propane

Authors

  • S. V. Khalameida Institute for Sorption and Problems of Endoecology of National Academy of Sciences of Ukraine
  • N. D. Konovalova Institute for Sorption and Problems of Endoecology of National Academy of Sciences of Ukraine
  • V. O. Zazhigalov Institute for Sorption and Problems of Endoecology of National Academy of Sciences of Ukraine
  • V. I. Zarko Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine

Keywords:

V2O5, MoO3, solid solution, hydrothermal modification, electroconductivity, dehydrogenation of propane

Abstract

The influence of conditions for V2O5-MoO3 catalysts hydrothermal treatment (HTT) by conventional and microwave heating on their physico-chemical and catalytic properties has been studied. The observed transformations have been investigated by XRD, FTIR, nitrogen adsorption, measurements of electroconductivity. The activity V-Mo-O samples in reaction of oxidative dehydrogenation of propane increases in row HTT-300°С > HTT-350°С > HTT-250°С according to changes of their conductivity G?10–5: 11 > 6 > 1 S/m.

References

1. Шиманская М.В., Лейтис Л.Я., Сколмейстере Р.А. и др. Ванадиевые катализаторы окисления гетероциклических соединений. – Рига: Зинатне, 1990. – 255 с.

2. Bielanski A., Najbar M. V2O5-MoO3 catalysts for benzene oxidation // Appl. Catal. A. – 1997. – V. 1. – P. 223 – 261.

3. Плясова Л.М., Зенковец Г.А., Оленькова И.П., Тарасова Д.В. Формирование фазового состава окисной ванадий-молибденовой системы при термическом разложении парамолибдата и метаванадата аммония // Изв. СО АН СССР. Сер. хим. наук. – 1980. – № 9, вып. 4. – С. 97–104.

4. Волков В.Л. Фазы внедрения на основе оксидов ванадия. – Свердловск: УНЦ АН СССР, 1987. – 180 с.

5. Гольдштейн Н.Д., Мищенко Ю.А., Гельбштейн А.И. Энергия связи поверхностного кислорода в системе V2O5 – MoO3 разных составов // Журн. физ. химии. – 1972. – Т. 46, № 1. – С. 106–110.

6. Волков В.Л. Исследование хемосорбции кислорода в системе V2O5 – MoO3 // Журн. физ. химии. – 1985. – Т. 59, № 2. – С. 428–432.

7. Parmaliana A., Sokolovskii V., Miceli D.and Giordano N. Highly effective vanadia-silica catalyst for propane oxidative dehydro-genation // Appl. Catal. A. – 1996. – V. 135. – P. L1–L5.

8. Klisinska A., Loridant S., Grzybowska B. et al. Effect of additives on properties of V2O5/SiO2 and V2O5/MgO catalysts. II. Structure and physicochemical properties of the catalysts and their correlations with oxidative dehydrogenation of propane and ethane // Appl. Catal A: General. – 2006. – V. 309. – P. 17–27.

9. Dai H., Bell A.T., Iglesia E. Effects of molybdena on the catalytic properties of vanadia domains supported on alumina for oxidative dehydrogenation of propane // J. Catal. – 2004. – V. 221. – P. 491–499.

10. Taylor S.H., Pollard A.J.J. Silica and boron nitride supported molybdenum and vanadium oxide catalysts for propane oxidation // Catal.Today. – 2003. – V. 81. – P. 179–188.

11. Tichy J. Oxidation of acrolein to acrylic acid over vanadium-molybdenum oxide catalysts // Appl. Catal A: General. – 1997. – V. 157. – P. 363–385.

12. Pless J.D., Bardin B.B., Kim H-S. et al. Catalytic oxidative dehydrogenation of propane over Mg-V/Mo oxides // J. Catal. – 2004. – V. 223. – P. 419–431.

13. Botella P., López-Nieto J.M., Solsona B. Preparation, characterization and catalytic behavior of a new TeVMoO crystalline phase // Catal. Lett. – 2002. – V. 78. – P. 383–387.

14. Lin M.M. Selective oxidation of propane to acrylic acid with molecular oxygen // Appl. Catal. A: General. – 2001. – V. 207. – P. 1–16.

15. Андрушкевич Т.В. Механизм каталитического действия оксидных систем в реакциях окисления альдегидов в карбоновые кислоты // Кинетика и катализ. – 1997. – Т. 38, № 2. – С. 289–300.

16. Ueda W., Oshihara K. Selective oxidation of light alkanes over hydrothermally synthesized Mo-V-M-O oxide catalysts // Appl. Catal. A. – 2000. – V. 200. – P. 135–143.

17. Skwarek E., Khalameida S., Janusz W. et al. Influence of mechanochemical activation on structure and some properties of mixed vanadium-molybdenum oxides // J. Therm. Anal. Calorim. – 2011. – V. 106. – P. 881–894.

18. Khalameida S., Sydorchuk V., Leboda R. et al. Physical-chemical transformations in the system V2O5-(NH4)2Mo2O7 under hydro-thermal conditions // Central Eur. J. Chem. – 2014. – V. 12. – P. 140–152.

19. Vitry D., Morikawa Y., Dubois J.L., Ueda W. Mo-V-Te-(Nb)-O mixed metal oxides prepared by hydrothermal synthesis for catalytic selective oxidations of propane and propene to acrylic acid // Appl.Catal A: Genera l. – 2003. – V. 251. – P. 411–424.

20. López-Nieto J.M., Botella P., Solsona B., Oliver J.M. The selective oxidation of propane on Mo-V-Te-Nb-O catalysts: The influence of Te-precursor // Catal.Today. – 2003. – V. 81. – P. 87–94.

21. Duc F., Gonthier S., Brunelli M., Trombe J.C. Hydrothermal synthesis and structure determi-nation of the new vanadium molybdenum mixed oxide V1.1Mo0.9O5 from synchrotron   X-ray powder diffraction data // J. Solid State Chem. – 2006. – V. 179. – P. 3591–3598.

22. Agterdenbos J., Eggink A.J.R. A rapid determination of the deviation from stoichiometry in vanadium pentoxide // Z. anorg. allg Chem. – 1972. – V. 388. – P. 177–180.

23. Pieters T.W.J., Kuilenburg J.M. Relationship between V4+ and Mo6+ contents in V2O5 doped with MoO3 // Z. anorg. allg. Chem. – 1973. – V. 399. – P. 170–174.

24. Mougin O., Dubois J.-L., Mathieu F., Rousset A. Metastable hexahonal vanadium molybdate study // J. Solid State Chem. – 2000. – V. 152. – P. 353–360.

25. Волков В.Л., Захарова Г.С., Бондаренкo В.М. Ксерогели простых и сложных поливанадатов. – Екатеринбург: Уральское отд. Ин-та химии твердого тела, 2001. – 195 с.

26. Фенелонов В.Б. Введение в физическую химию формирования супрамолекулярной структуры адсорбентов и катализаторов. – Новосибирск: СО РАН, 2004. – 440 с.

27. Юхневич Г.В. Инфракрасная спектроскопия воды. – Москва, 1973. – 207 с.

28. Накомото К. Инфракрасные спектры неорганических соединений. – Москва: Мир, 1966. – 411 с.

29. Allersma T., Hakim R., Kennedy T.N., Mackenzie J.D. Structure and physical properties of solid and liquid vanadium pentoxide // J. Chem. Phys. – 1967. – V. 46. – P. 154–160.

30. Нейман А.Я., Барсанов С.Ю. Новые данные о механизме массопереноса при твердофазных реакциях. III. Взаимодействие оксидов с низкой поверхностной энергией (реакция между V2O5 и МоО3) // Кинетика и катализ. – 1999. – T. 40, № 1. – С. 50–57.

31. Burzo E., Stanescu L., Ardelean I., Chipara M. Soluţii solide pe bază de V2O5. II. Proprietăţi fizice // Revista Chim. – 1980. – V. 31. – P. 351–357.

32. Shaporev A.S., Ivanov V.K., Baranchikov A.E., Tret’yakov Yu.D. Microwave-assisted hydro-thermal synthesis and photocatalytic activity of ZnO // Inorg. Mater. – 2007. – V. 43. – P. 35–39.

33. Manoharan S. S., Prasanna S.S.J., Rao M.L., Sahu R.K. Microwave-assisted synthesis of fine particle oxides employing wet redox mixtures // J. Am. Ceram. Soc. – 2002. – V. 85. – P. 2469–2471.

34. Vislovskiy V.P., Suleimanov T.E., Sinev M.Yu. et al. On the role of heterogeneous and homogeneous processes in oxidative dehydrogenation of C3-C4 alkanes // Catal Today. – 2000. – V. 61. – P. 287–293.

35. Solsona B., Blasco T., Lopez Nieto J.M. et al. Vanadium oxide supported on mesoporous MCM-41 as selective catalysts in oxidative dehydrogenation of alkanes // J. Catal. – 2001. – V. 203. – P. 443–452.

36. Monaci R., Rombi E., Soinas V. et al. Oxida-tive dehydrogenation of propane over V2O5/TiO2/SiO2 catalysts obtained by grafting titanium and vanadium alkoxides on silica // Appl. Catal. A: General. – 2001. – V. 214. – P. 203–212.

37. Karakoulia S.A., Triantafyllidis K.S., Lemoni-dou A.A. Preparation and characterization of vanadia catalysts supported on non-porous, microporous and mesoporous silicates for oxidative dehydrogenation of propane (ODP) // Micropor. Mesopor. Mater. – 2008. – V. 110. – P. 157–166.

Downloads

How to Cite

KHALAMEIDA, S. V.; KONOVALOVA, N. D.; ZAZHIGALOV, V. O.; ZARKO, V. I. Hydrothermal Modification of Vanadium-Molybdenym Oxide Catalysts for Oxidative Dehydrogenation of Propane. Chemistry, Physics and Technology of Surface, [S. l.], v. 5, n. 2, p. 164–173, 2014. Disponível em: https://cpts.com.ua/index.php/cpts/article/view/276. Acesso em: 14 jul. 2025.

Issue

Vol. 5 No. 2 (2014): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni

Section

Articles

License

  1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
  2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
  3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.