Electrophysical Properties of Polymer Composites on the Basis of Multiwalled Carbon Nanotubes Synthesized on a Basalt Scale

Authors

  • R. V. Mazurenko Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • S. V. Zhuravsky Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • G. M. Gunya Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • G. P. Prikhod’ko Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • S. N. Makhno Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • P. P. Gorbik Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine
  • M. T. Kartel Chuiko Institute of Surface Chemistry of National Academy of Sciences of Ukraine

Keywords:

multiwalled carbon nanotubes, polymer composites, conductivity, dielectric permittivity

Abstract

The electrophysical properties of polymer composites (PC) based on polychlorotrifluoroethylene (PCTFE) filled multiwalled carbon nanotubes (MWCNT) synthesized on the surface of basalt scale (BS) have been studied in the superfrequency range and low-frequencies. Concentration of MCNT relative to basaltic catalyst is 0.32 volume fractions. It has been shown that the values of real and imaginary рarts of the complex permittivity in the superfrequency range and electrical conductivity at low frequencies depend nonlinearly on the volume content of MWCNT in composites. The percolation threshold of system 0.32MWCNT/BS–PCTFE has been defined and its value is 0.013 volume fractions.

References

1. Дьячков П.Н. Элекронные свойства и применение нанотрубок. – Москва: БИНОМ Лаборатория знаний. – 2011. – 488 с.

2. Бадамшина Э.Р., Гафурова М.П., Эстрин Я.И. Модифицирование углеродных нанотрубок и синтез полимерных композитов с их участием. // Успехи химии. – 2010. – Т. 79, № 11. – С. 1027–1064.

3. Gaufres E., Izard N., Roux X.Le. et al. Optical microcavity with semiconducting singlewall carbon nanotubes // Opt. Express. – 2010. – V. 18, N 6. – Р. 5740–5745.

4. Benjamin S. Carbon nanotube applications for tissue engineering // Biomaterials. – 2007. – V. 28. – P. 344–353.

5. Chaudhary S. Hierarchical placement and associated optoelectronic impact of carbon nanotubes in polymer - fullerene solar cells // Nano Letters. – 2007. – V. 7. – P. 1973–1979.

6. Hillebrenner H. Template synthesized nanotubes for biomedical delivery applications // Nanomedicine. – 2006. – V. 1. – P. 39–50.

7. Stephan T. Nanotechnology safety concerns revisited // Toxicological Sciences. – 2008. – V. 101. – P. 4–21.

8. Батурин А.С., Казин А.А., Лейченко А.С. и др. Метод локализованного синтеза высокоориентированных углеродных нанотрубок для применения в вакуумной микроэлектронике // Труды МФТИ. – 2013. – Т. 5, № 1. – С. 10–15.

9. Борисевич К.О., Жданок С.А., Буяков И.Ф. и др. Установка для получения углеродных наноматериалов CVD методом в условиях дуговой плазмы // Наносистемы, наноматериалы, нанотехнологии. – 2011. – Т. 9, № 1. – С. 161–166.

10. Раков Э.Г. Методы получения углеродных нанотрубок // Успехи химии. – 2000. – Т. 69, № 1. – С. 41–59.

11. Kim M.T., Rhee K.Y., Park S.J., Hui D. Effects of silane-modified carbon nanotubes on flexural and fracture behaviors of carbon nanotube-modified epoxy/basalt composites // Composites: Part B. – 2012. – V. 43. – Р. 2298–2302.

12. Ганюк Л.М., Ігнатков В.Д., Махно С.М., Сорока П.М. Дослідження діелектричних властивостей волокнистого матеріалу // Укр. фіз. журнал. – 1995. – Т. 40, № 6. – С. 627–629.

13. Павлов Л.П. Методы определения параметров полупроводниковых материалов. – Москва: Высшая школа. 1987.– 239 с.

14. Mazov I., Kuznetsov V.L., Simonova I.A. et al. Oxidation behavior of multiwall carbon nanotubes with different diameters and morphology // Appl. Surf. Sci. – 2012. – V. 258. – P. 6272–6280.

15. Глебова Н.В., Нечитайлов А.А., Кукушкина Ю.А., Соколов В.В. Исследование термического окисления углеродных наноматериалов // Письма в ЖТФ. – 2011. – Т. 37, вып. 9. – С. 97–104.

16. Москалюк О.А., Алешин А.Н., Цобкалло Е.С. и др. Электропроводность полипропиленовых волокон с дисперными углеродными наполнителями // Физика твердого тела. – 2012. – Т. 54, Вып. 10. – С. 1993–1998.

17. Котенок О.В., Махно С.М., Приходько Г.П., Семенцов Ю.І. Електрофізичні властивості системи політетрафторетилен-вуглецеві нанотрубки // Поверхость. Сб.научных тр. / Ин-т химии поверхности им. А.А. Чуйко НАН Украины. – Киев: Наукова думка, 2009. – вып. 1(16). – С. 213–218.

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(1)
Mazurenko, R. V.; Zhuravsky, S. V.; Gunya, G. M.; Prikhod’ko, G. P.; Makhno, S. N.; Gorbik, P. P.; Kartel, M. T. Electrophysical Properties of Polymer Composites on the Basis of Multiwalled Carbon Nanotubes Synthesized on a Basalt Scale. Him. Fiz. Tehnol. Poverhni 2014, 5, 220-225.

Issue

Vol. 5 No. 2 (2014): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni

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Articles

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