Написати автору Наночастинки гідрофосфату цирконію, армовані слабкокислотним катіонообмінним полімером
DOI: https://doi.org/10.15407/hftp09.01.026
Анотація
Слабкокислотну катіонообмінну смолу модифіковано наночастинками гідрофосфату цирконію. Матеріали досліджено методами еталонної контактної порометрії та трансмісійної електронної мікроскопії. У фазі полімера знайдено як неагреговані наночастинки (5–15 нм), так і агрегати (від 250 нм до декількох мікрон). Наночастинки у кластерах та каналах полімера пригнічують дисоціацію карбоксильних груп, що зумовлено протиіонами (H+) подвійного електричного шару навколо частинок. Це призводить до трансформації пористої структури полімера – внесок мікропор до загальної пористості зростає. Сформовані додаткові селективні центри обумовлюють більш сильну взаємодію з поверхнею молекул діамантового зеленого у порівнянні з немодифікованим полімером. Досліджено вилучення іонів Ni(II) з води, яка містить іони жорсткості, композит демонструє у два рази більшу ємність до проскока, ніж полімер. Модифікатор також полегшує регенерацію слабкокислотного іоніту.
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DOI: https://doi.org/10.15407/hftp09.01.026
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