ХІМІЯ, ФІЗИКА ТА ТЕХНОЛОГІЯ ПОВЕРХНІ

ISSN 2518-1238 (Online), ISSN 2079-1704 (Print)

Синтезовано ряд багатофункціональних композитних адсорбентів на основі гідратованого діоксиду цирконію. Неорганічний іоніт містив наночастинки окисненого графену (ОГ), кількість модифікатора становила 0.5–7 мас. %. Композити досліджували методами трансмісійної електронної мікроскопії та адсорбції-десорбції азоту. Встановлено, що збільшення вмісту ОГ призводить до зменшення мікропористості, при цьому зростає мезо- та макропористість, а загальний об’єм пор збільшується з 0.49 до 0.62 см³ г^-1. Міцність на розчавлювання експоненціально зменшується зі збільшенням об’єму пор. Досліджено вилучення фенолу з водопровідної води. Показано, що адсорбційна ємність досягає 0.15–0.85 (фенол), 0.5–0.85 (Ca²⁺ і Mg²⁺), 0.005–0.045 (SO₄^2–) ммоль г^–1. Коли вміст OГ в композитах становить        0.5–2 %, ця вуглецева добавка покращує адсорбцію катіонів і органічних молекул у порівнянні з гідратованим діоксидом цирконію. Подальше збільшення кількості ОГ істотно не впливає на адсорбцію внаслідок зменшення питомої площі поверхні композитів. Стверджується, що оптимальний вміст модифікатора, що забезпечує максимальний приріст адсорбції, становить 2 %. Цей композит отримано у вигляді великих гранул (0.3–0.5 мм), їхня міцність на розчавлювання становить 9 атм. Матеріал використовували для видалення пестицидів (ацетоміпріду, карбоксину, епоксіконазолу і тіаметоксаму) з водного багатокомпонентного розчину в статичних умовах. Залишковий вміст карбоксину і епоксіконазолу, молекули яких містять бензольні кільця, нижче гранично допустимої концентрації. Близько 50 % токсичних речовин видаляються протягом першої години. Після п’яти циклів адсорбції-регенерації не було виявлено погіршення адсорбції пестицидів.

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