Antiozonate activity of mono- and bimetal complexes of 3d-metals with salicylaliminopropyl groups immobilized on nanosilica

  • T. L. Rakyts'ka Mechnickov National University of Odessa
  • A. S. Truba Mechnickov National University of Odessa
  • E. O. Radchenko Taras Shevchenko National University
  • A. A. Golub Taras Shevchenko National University
DOI: https://doi.org/10.15407/hftp07.01.065
Keywords: low-temperature ozone decomposition, salicylaliminopropylaerosil, mono- and bimetal complexes

Abstract

The influence of metal nature and synthesis method (joint and separate adsorption) of bimetal complexes [M1-M2-L1] based on Mn(II), Co(II), Cu(II), Zn(II) and salicylaliminopropylaerosil on their activity in ozone decomposition reaction has been studied. The activity of monometal complexes is decreased in sequence Mn(ІІ)>>Сo(ІІ)>Cu(ІІ)>Zn(ІІ) and under introduction of second metal the antiozonate properties of bimetal complexes are reduced. It is pointed out that bimetal complexes synthesized by joint sorption are more active than those prepared by means of separate adsorption of metal ions.

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How to Cite
RAKYTS’KA, T. L.; TRUBA, A. S.; RADCHENKO, E. O.; GOLUB, A. A. Antiozonate activity of mono- and bimetal complexes of 3d-metals with salicylaliminopropyl groups immobilized on nanosilica. Chemistry, Physics and Technology of Surface, v. 7, n. 1, p. 65-72, 11.
Issue
Vol. 7 No. 1 (2016): Chemistry, Physics and Technology of Surface / Himia, Fizika ta Tehnologia Poverhni
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