Chemistry, Physics and Technology of Surface, 2015, 6 (3), 318-325.

Kinetics of the elementary acts of electrochemical reactions at the «solid–electrolyte» interface



DOI: https://doi.org/10.15407/hftp06.03.318

V. V. Soloviev, S. S. Kovalenko

Abstract


Within the framework of the quantum-mechanical theory of elementary acts of non-adiabatic electrochemical reactions and using the model of isotropic spherically symmetric band, the calculation of the discharge current of ions at the “solid–electrolyte” interface has been carried out. It is shown that our results generalize the analogical formulae, which are available in the literature. The average densities of states in the valence band and in the conduction band of the solid electrode under the heterogeneous charge transfer are found.

Keywords


elementary act of red-ox reactions; quantum-mechanical theory; density of states

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References


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DOI: https://doi.org/10.15407/hftp06.03.318

Copyright (©) 2015 V. V. Soloviev, S. S. Kovalenko

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