Хімія, фізика та технологія поверхні, 2015, 6 (1), 147-164.

Координаційні сполуки металів життя та біолігандів як модельні додатки до екобезпечних мастильних композицій



DOI: https://doi.org/10.15407/hftp06.01.147

L. I. Koval, V. I. Dzyuba, O. L. Ilnitska, V. I. Pekhnyo, O. A. Mishchuk

Анотація


Обґрунтовано актуальність створення нових екологічно безпечних біобазованих мастильних матеріалів і, відповідно, нового покоління поліфункціональних додатків до них на основі металів життя та біолігандів. Розглянуто методи синтезу модельних комплексів-додатків Mg (II), Cu (II) і Mo (VI) з b-дикарбонільними лігандами та гідроксамовими кислотами, особливості їх молекулярної будови та трибологічні властивості в розчині етиллаурату (базова олива рослинного походження). Виявлено, що мідь- та молібденвмісні змащувальні додатки впливають на мікроструктуру і склад поверхонь та приповерхневих шарів зони тертя, внаслідок проникнення їх елементів як легувальних домішок вглиб поверхневого шару зразків пар тертя.


Ключові слова


поверхня тертя; модельні додатки (присадки); трибологічні властивості; протизношувальні наношари; трибодифузія; екобезпечні мастильні матеріали; базові оливи рослинного походження; магній; мідь; молібден; біоліганди

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Посилання


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DOI: https://doi.org/10.15407/hftp06.01.147

Copyright (©) 2015 L. I. Koval, V. I. Dzyuba, O. L. Ilnitska, V. I. Pekhnyo, O. A. Mishchuk